| Pos | Class | Driver | Team | Car | Time | Gap | To 1st |
| 1. | LMP1 | Gene/Minassian | Team Peugeot Total | Peugeot 908 HDi | 1:31.528 | | |
| 2. | LMP1 | Sarrazin/Lamy | Team Peugeot Total | Peugeot 908 HDi | 1:32.174 | 0.646 | 0.646 |
| 3. | LMP1 | Capello/McNish | Audi Sport Team Joest | Audi R10 TDi | 1:33.193 | 1.019 | 1.665 |
| 4. | LMP1 | Rockenfeller/Premat | Audi Sport Team Joest | Audi R10 TDi | 1:33.330 | 0.137 | 1.802 |
| 5. | LMP1 | Charouz/Mucke | Charouz Racing System | Lola-Aston Martin | 1:34.170 | 0.840 | 2.642 |
| 6. | LMP1 | Panis/Lapierre | Team Oreca Matmut | Courage-Oreca LC70-Judd | 1:35.303 | 1.133 | 3.775 |
| 7. | LMP1 | Campbell-Walter/Hall | Creation AIM | Creation CA07-AIM | 1:35.869 | 0.566 | 4.341 |
| 8. | LMP1 | Ortelli/Ayari | Team Oreca Matmut | Courage-Oreca LC70-Judd | 1:35.891 | 0.022 | 4.363 |
| 9. | LMP1 | Collard/Boullion | Pescarolo Sport | Pescarolo 01-Judd | 1:36.117 | 0.226 | 4.589 |
| 10. | LMP2 | van Merksteijn/Verstappen | van Merksteijn Motorsport | Porsche RS Spyder | 1:36.842 | 0.725 | 5.314 |
| 11. | LMP1 | Kerr/Jouanny | Creation AIM | Creation CA07-AIM | 1:37.062 | 0.220 | 5.534 |
| 12. | LMP1 | Primat/Tinseau | Pescarolo Sport | Pescarolo 07-Judd | 1:37.229 | 0.167 | 5.701 |
| 13. | LMP1 | de Castro/Burgueno | Epsilon-Euskadi | Epsilon Euskadi-Judd | 1:37.485 | 0.256 | 5.957 |
| 14. | LMP2 | Lienhard/Theys/Lammers | Horag Racing | Porsche RS Spyder | 1:37.845 | 0.360 | 6.317 |
| 15. | LMP2 | Belicchi/Zacchia/Pompidou | Speedy Racing Team Sebah | Lola B08/80-Judd | 1:38.180 | 0.335 | 6.652 |
| 16. | LMP2 | Nielsen/Elgaard | Team Essex | Porsche RS Spyder | 1:38.346 | 0.166 | 6.818 |
| 17. | LMP2 | Barazi/Vergers/Rees | Barazi Epsilon | Zytek 07S-Zytek | 1:38.570 | 0.224 | 7.042 |
| 18. | LMP1 | Tappy/Short/Ickx | Rollcentre Racing | Pescarolo 04-Judd | 1:38.619 | 0.049 | 7.091 |
| 19. | LMP2 | Erdos/Newton | RML | MG Lola EX265-MG | 1:38.697 | 0.078 | 7.169 |
| 20. | LMP2 | Ojjeh/Gosselin/Schroyen | Trading Performance | Zytek 07S-Zytek | 1:39.861 | 1.164 | 8.333 |
| 21. | LMP2 | Kane/Foster | Embassy Racing | WF01-Zytek | 1:40.196 | 0.335 | 8.668 |
| 22. | LMP2 | Haberfeld/Hughes | Embassy Racing | WF01-Zytek | 1:40.385 | 0.189 | 8.857 |
| 23. | LMP2 | Ragues/Lahaye | Saulnier Racing | Pescarolo 06-Judd | 1:40.748 | 0.363 | 9.220 |
| 24. | LMP2 | Amaral/Pla | Quifel-ASM | Lola B05/40-AER | 1:40.763 | 0.015 | 9.235 |
| 25. | LMP1 | Nicolet/Faggionato/Hein | Saulnier Racing | Pescarolo 05-Judd | 1:40.865 | 0.102 | 9.337 |
| 26. | LMP2 | de Pourtales/Noda | Kruse Schiller Motorsport | Lola-Mazda | 1:41.007 | 0.142 | 9.479 |
| 27. | LMP2 | Lueders/Petersen/Rostan | Bruichladdich Radical | Radical SR9-AER | 1:41.785 | 0.778 | 10.257 |
| 28. | GT1 | Beretta/Moreau/Goueslard | Luc Alphand Aventures | Corvette C6.R | 1:44.102 | 2.317 | 12.574 |
| 29. | GT1 | Garcia/Enge | Team Modena | Aston Martin DBR9 | 1:44.389 | 0.287 | 12.861 |
| 30. | LMP2 | Didaio/Francioni/Savoldi | Racing Box | Lucchini-Judd | 1:44.471 | 0.082 | 12.943 |
| 31. | GT1 | Dumez/Blanchemain/Manopoulous | Luc Alphand Aventures | Corvette C6.R | 1:45.507 | 1.036 | 13.979 |
| 32. | GT1 | Rusinov/Kox | IPB Spartak Racing | Lamborghini Murcielago GT | 1:46.243 | 0.736 | 14.715 |
| 33. | GT2 | Bell/Bruni | Virgo Motorsport | FerrariF430 GT | 1:49.006 | 2.763 | 17.478 |
| 34. | GT2 | Lieb/Davison | Felbermayr-Proton | Porsche 997 GT3 RSR | 1:49.227 | 0.221 | 17.699 |
| 35. | GT2 | Kaffer/Ehret | Farnbacher Racing | Ferrari F430 GT | 1:49.839 | 0.612 | 18.311 |
| 36. | GT2 | Narac/Lietz | IMSA Performance Matmut | Porsche 997 GT3 RSR | 1:50.008 | 0.169 | 18.480 |
| 37. | GT2 | Daoudi/Aucott | JMB | Ferrari F430 GT | 1:50.346 | 0.338 | 18.818 |
| 38. | GT2 | Westbrook/Nielsen/Simonsen | Farnbacher Racing | Porsche 997 GT3 RSR | 1:50.401 | 0.055 | 18.873 |
| 39. | GT2 | Daniels/Sugden/Palttalla | James Watt Automotive | Aston Martin Vantage V8 | 1:50.953 | 0.552 | 19.425 |
| 40. | GT2 | Balandras/Lecourt/Belloc | IMSA Performance Matmut | Porsche 997 GT3 RSR | 1:51.057 | 0.104 | 19.529 |
| 41. | GT2 | Kelleners/Vassiliev/Dumbreck | Snoras Spyker Squadron | Spyker C8 Lavoilette GT2R | 1:51.217 | 0.160 | 19.689 |
| 42. | GT2 | Felbermayr/Felbermayr/Ried | Felbermayr-Proton | Porsche 997 GT3 RSR | 1:51.468 | 0.251 | 19.940 |
| 43. | GT2 | Chiesa/Leuenberger | Speedy Racing Team | Spyker C8 Lavoilette GT2R | 1:52.330 | 0.862 | 20.802 |
| 44. | GT2 | Basso/Casadei/Kutemann | JMB | Ferrari F430 GT | 1:53.174 | 0.844 | 21.646 |
| 45. | LMP2 | Salini/Salini/Roussel | WR/Salini | WR-Zytek | No time | | |
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